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-Heidi

Do you know what the approx. carbo count is for your kefir beer? I don't

understand how it is lower in carbs when beer is so high in carbs.

Jafa

Heidi Schuppenhauer <heidis@...> wrote:

>Cool.

>

>Although of course, now my still-vaguely-overactive imagination is

>imagining, after having a bit of a 'discussion' with Dr. Ron about me

>drinking 'too much' fruit juice, having another discussion in which I just

>tell him I've solved that 'problem' and now I just spend all day drinking

>Hooch. :-D

Oh, " Hooch " sounds so STRONG. Really, kefir beer is very mild.

I like it because pop is SOOOO sweet (as is fruit juice) and this

loses most of the sugar. But you'd have to drink a gallon or

so to really get a buzz, and it is VERY filling. However, the amount

of alcohol is directly related to the amount of sugar you add

to begin with ... so if you want it milder, cut the juice with water

or add less sugar (depending how you are making it).

-- Heidi (of Hooch fame ... ;--)

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In a message dated 3/19/04 1:16:46 PM Eastern Standard Time,

heidis@... writes:

> Lactic acid may or may not turn into glucose in the liver, depending

> on the kind of lactic acid (there are 2 isomers) but in general it

> seems to be a health promoter and a substance that regulates

> insulin in the body.

Isn't only one of the isomers produced biologically? That is, the one with L

optical activity? (I'm not disputing only some of it turns to glucose)

> Alcohol REALLY depends on your philosophy ... statistically

> folks who get more calories from alcohol are skinnier, whatever

> that means. It certainly doesn't seem to act like a starch (quick

> digesting starches make me hungrier the next day).

I don't get any problems from carbs except gut problems. I noticed that some

beers, and always ones I get from the bar, seem to give me gut problems, and

some, especially the unfiltered ones I drink at home, don't give me any

problems. Heineken, for example, seems to have induced diarrhea for me on more

than

one occasion.

Chris

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>-Heidi

>

>Do you know what the approx. carbo count is for your kefir beer? I don't

understand how it is lower in carbs when beer is so high in carbs.

>

>Jafa

Oh, that's a loaded question. The sugars turn to lactic acid and alcohol ...

both

of which can count as carbs, depending on your carb philosophy. It's

lower in sugars for sure (and I don't like really sweet stuff) and my carb

philosophy only counts starches and sometimes sugars.

Lactic acid may or may not turn into glucose in the liver, depending

on the kind of lactic acid (there are 2 isomers) but in general it

seems to be a health promoter and a substance that regulates

insulin in the body.

Alcohol REALLY depends on your philosophy ... statistically

folks who get more calories from alcohol are skinnier, whatever

that means. It certainly doesn't seem to act like a starch (quick

digesting starches make me hungrier the next day).

-- Heidi Jean

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In a message dated 3/19/04 7:10:14 PM Eastern Standard Time,

heidis@... writes:

> Each type of bacteria produces one isomer or another. Acidophilus

> produces the one that is hard to metabolize (I forget if that is the R or L

> version).

I assume it's the D version. R is opposed to S, not L. R and S deal with

the actual shape, whereas D and L deal with optical activity. If an R has D

optical activity, the S isomer will have L optical activity at equal magnitude,

and vice versa, but there is no connection in the sense that some R's have D

activity and some R's have L activity, and of any given magnitude.

Biological systems, at least animals and plants anyway, seem to use the L

form exclusively (almost exclusively?), which is very, very interesting,

considering the lack of correlation to the actual structure.

Chris

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In a message dated 3/19/04 6:19:22 PM Eastern Standard Time,

darkstar@... writes:

> (I should have said some kinds of bacteria make L and some make D.

> (For all I know, some make both.) Too much D can apparently cause

> acidosis problems for some people, for example people with short

> bowel syndrome. But it's been a while since I read about it; I'd

> have to look at google or pubmed again. It was complicated and there

> were some disagreements.)

So would fermenting actually decrease caloric value due to malabsorption?

Chris

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>

> Isn't only one of the isomers produced biologically? That is, the

one with L optical activity? (I'm not disputing only some of it

turns to glucose)

>

>

Only the L is made by us. But some bacteria make D.

Marty

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--- In , " darkstardog " <\

> Only the L is made by us. But some bacteria make D.

>

(I should have said some kinds of bacteria make L and some make D.

(For all I know, some make both.) Too much D can apparently cause

acidosis problems for some people, for example people with short

bowel syndrome. But it's been a while since I read about it; I'd

have to look at google or pubmed again. It was complicated and there

were some disagreements.)

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>

>

>> Lactic acid may or may not turn into glucose in the liver, depending

>> on the kind of lactic acid (there are 2 isomers) but in general it

>> seems to be a health promoter and a substance that regulates

>> insulin in the body.

>

>Isn't only one of the isomers produced biologically? That is, the one with L

>optical activity? (I'm not disputing only some of it turns to glucose)

Each type of bacteria produces one isomer or another. Acidophilus

produces the one that is hard to metabolize (I forget if that is the R or L

version).

This came up some time ago because some people get an

overgrowth of acidophilus and end up with acidosis from that

lactic acid since it builds up in their system. Good argument for

NOT using acidophilus supplements! If you take the supplements

while taking an antibiotic (to replenish your gut) they can just take

over. Bad stuff.

The recommendation was to use a mix of bacteria ... which is

why I think kefir is better than any probiotic supplement.

> I don't get any problems from carbs except gut problems. I noticed that some

>beers, and always ones I get from the bar, seem to give me gut problems, and

>some, especially the unfiltered ones I drink at home, don't give me any

>problems. Heineken, for example, seems to have induced diarrhea for me on more

than

>one occasion.

Funny, that just came up here. It seems beer consumption is associated

with several known downsides (one beer per day raises the chance of

getting gout by 49%, for example, and raises a woman's chance of breast

cancer) but wine is not associated with those downsides. One beer makes

me sicker than a piece of bread, and quicker, too ... but wine, even in

overdose amounts, seems to have no effect other than to my thinking

ability. I suspect the alcohol carries the proteins in the beer (from grains and

yeast)

straight into the blood. Grapes don't have any weird proteins, and the yeast

dies and sinks to the bottom in wine making (plus most of it is filtered).

Commercial beers, who knows? There is all kinds of stuff in that!

I never drank them though. I'd think they have less carbs than the non-filtered

high class ones though.

Kefir beer does affect my gut, big time ... it's effect is to normalize

things though. If I drink hooch every night I have perfectly normal

gut function, otherwise it varies (though it's not near as bad

as when I was eating wheat).

-- Heidi Jean

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In a message dated 3/19/04 11:02:30 PM Eastern Standard Time,

heidis@... writes:

> Oh that's so confusing .... here we were referring to them as R and L (for

> Right and Left) and no one corrected it ... Maybe we should use + and -.

> Anyway, in some articles it mentions that the - form can kill rats (and

> people) ...

> it's pretty toxic at higher dosages, though the kidneys clear it from the

> blood.

> So yeah, you are right, the - form is basically " less calories " because it

> is

> excreted. Some of the + form is excreted too though.

(optical activity)

D is +

L is -

(structure)

R and S are independent of the former two.

R means " right " and S means " left " because S stands for " sinister " and

left-handed people are evil. Really-- that's where it comes from (Roman times).

D means " dextrorotatory " which means right, and L means " levorotatory " which

means left, but this " right and left " refers to optical activity, whereas R

and S indicate structure.

_________

These are used for chiral centers, which is where you have a carbon (I think

it can be non-carbon too, if you have the same criteria satisfied for another

sp3 hybridized atom [which basically means an atom that has four bonds]) with

four DIFFERENT atoms attached to it. What the other atoms is attached to

makes a difference, so if the carbon is attached to two carbons, but one carbon

is

a CH3 and one is a CH2CH2CH3 they're considered " different. "

Then you take the hydrogen, or if there's no hydrogen, the atom with the

lowest atomic number, and stick it in the background. Since the carbon with

it's

four bonded atoms is tetrahedral (has four sticking out at equal angles of 120

degrees), that leaves three atoms sticking out into the foreground.

Now you rank the atoms in order of their atomic number. If there are two of

the same atoms, you rank them according to what's attached to them (so

CH2CH2CH3 would be ranked higher than CH3). You give the highest ranking " 1 "

and

then proceed down the order of atomic number with each rank from 1.

If you need to count CLOCKWISE to count " 1, 2, 3 " then you have the R

configuration. If you need to count COUNTER CLOCKWISE to count " 1, 2, 3 " then

you

have the S configuration.

That's stereoisomerism.

_________

Optical activity is totally different. You fill a polarimeter with a

chemical. It sends light through a filter that filters out any angled light

rays, so

the light travels in straight lines through the tubes, in a verticle

allignment (so it only travels through one narrow strip in the middle of the

tube.)

On the opposite end, you have another verticle filter, that you allign with the

first, so that if there is no refraction of light rays, the light will pass

right through. But when you fill the polarimeter tube with a chemical, it will

defract the light somehow, and that verticle line will get rotated. So you

have to rotate the second filter until the light passes through.

If you rotate it to the LEFT, you have L or - optical activity. If you

rotate it to the RIGHT, you have D or + optical activity.

________

Optical activity and stereoisomerism are unrelated, in that an R

configuration can have D optical activity of, say a magnitude of 0.5, while

another R

configuration of a different chemical might have D optical activity of 0.8,

while

yet another R configurated chemical might have L optical activity of 0.5, etc.

There's no relation.

BUT, if one stereoisomer has a D optical activity of 0.5, the mirror image of

that isomer will have L optical activity of 0.5. If the S configuration of

any giving molecule has L optical activity of 0.7, the R configuration of the

same molecule will have D optical activity of 0.7.

So R and S don't themselves have any direct relation to optical activity, but

for any given optical activity for a given isomer, the opposite isomer will

have the opposite optical activity of the same magnitude.

Hope that helps,

Chris

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>I assume it's the D version. R is opposed to S, not L. R and S deal with

>the actual shape, whereas D and L deal with optical activity. If an R has D

>optical activity, the S isomer will have L optical activity at equal magnitude,

>and vice versa, but there is no connection in the sense that some R's have D

>activity and some R's have L activity, and of any given magnitude.

Oh that's so confusing .... here we were referring to them as R and L (for

Right and Left) and no one corrected it ... Maybe we should use + and -.

Anyway, in some articles it mentions that the - form can kill rats (and people)

....

it's pretty toxic at higher dosages, though the kidneys clear it from the blood.

So yeah, you are right, the - form is basically " less calories " because it is

excreted. Some of the + form is excreted too though.

-- Heidi Jean

http://www.inchem.org/documents/jecfa/jecmono/40abcj44.htm

When 0.35 per cent. DL-lactic acid was administered to healthy

babies from the tenth to the twentieth day of life, a three-fold

increase in the urinary excretion of the physiological L(+)-lactic

acid and a twelve-fold increase in the D(-)-lactic acid was observed.

On withdrawing lactic acid from the diet the level of lactic acid

excreted in the urine returned to normal. Since the racemic mixture

used consisted of 80 per cent. of the L(+) and 20 per cent. of the

D(-) forms it seems that the metabolism of the D(-) form by the young

full-term baby is more difficult than the L(+) form. The increase in

the urinary excretion of either form of lactic acid indicated that the

young infant cannot utilize lactic acid at a rate which can keep up

with 0.35 per cent. in the diet. A number of babies could not tolerate

lactic acid. In such cases there was rapid loss of weight, frequent

diarrhoea, reduction of plasma bicarbonate and increased excretion of

organic acids in the urine. All these effects were reversed on

withdrawing lactic acid from the diet (Droese & Stolley, 1965).

http://www.acponline.org/journals/annals/01jun95/acidosis.htm

Main Results: A patient had several episodes of Dlactic

acidosis after receiving oral antibiotics. Stool

cultures yielded Lactobacillus acidophilus resistant

to the implicated agents. Provocative challenge with

dietary carbohydrate alone, in the absence of

antibiotics, failed to reproduce the syndrome.

Conclusions: Oral antibiotics may induce D-lactic

acidosis in patients with the short-bowel syndrome

by promoting the overgrowth of resistant D-lactateproducing

organisms. Interactions between

carbohydrate intake and antibiotic use are likely

determinants in the development of this syndrome.

Periodic use of stool cultures with antimicrobial

susceptibility testing may assist in the management

of these patients by optimizing the selection of

antimicrobial agents.

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>

> >-Heidi

>

> Oh, that's a loaded question. The sugars turn to lactic acid and alcohol

....and acetic acid, lets not forget the acetobacter bacteria in kefir grains :o)

Bruce

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>> Oh, that's a loaded question. The sugars turn to lactic acid and alcohol

>

> ...and acetic acid, lets not forget the acetobacter bacteria in kefir grains

:o)

>

>Bruce

Oh yeah! And if you leave the hooch out for month or two the alcohol goes

to acetic acid and you get some wonderful vinegar. It is definitely

VINEGAR ... acetic ... not just sour lactic acid. I wonder if the lactic

acid turns to acetic acid too? I use " kimchi juice " for vinegar too

but the taste is quite different, because the sour is mainly

from lactic acid.

-- Heidi Jean

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In a message dated 3/20/04 11:14:03 PM Eastern Standard Time,

heidis@... writes:

> Thanks! Now I get it: it IS " right " and " left " but in Latin ...

>

Right, er... correct, only it's important not to distinguish the structural

" right " and " left " from the *optical* " right " and " left, " so we can't mix up

R/S with D/L.

Chris

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>R means " right " and S means " left " because S stands for " sinister " and

>left-handed people are evil. Really-- that's where it comes from (Roman

times).

>

>D means " dextrorotatory " which means right, and L means " levorotatory " which

>means left, but this " right and left " refers to optical activity, whereas R

>and S indicate structure.

Thanks! Now I get it: it IS " right " and " left " but in Latin ...

-- Heidi Jean

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